Digging in the extension's source, I can see this key is set in common.js. I am a bit concerned this advertises that I have the extension installed, and that websites may be able to tell the extension to do something nefarious, like exfiltrate my browsing history. (But I don't have the skills to prove this one way or the other.)
Also, the extension is making various calls to an API, e.g. apparently fetching a list of redirects to implement.[2]
I don't know what else it's doing (I suspect rewriting shopping links to insert the creator's affiliate tags) but needless to say I've uninstalled it for now.
[0]https://chrome.google.com/webstore/detail/user-agent-switcher-for-g/ffhkkpnppgnfaobgihpdblnhmmbodake
[1]https://chrome.google.com/webstore/detail/user-agent-switcher-for-c/djflhoibgkdhkhhcedjiklpkjnoahfmg
[2]http://api.useragentswitcher.org/api/redirect2list?data-wid=1